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#272736 - 06/20/08 07:40 PM Tequila!!
Helice Administrator Offline
Administrator

Registered: 09/01/97
Loc: CT, US
Tequila is surprise raw material for diamond films

From a story found here: http://tinyurl.com/43xsw9 at the NewScientist.com news service.

Quote:
If you were looking for a new way to make semiconducting diamond, you might not have thought of starting with tequila. But the potent spirit turns out to be excellent raw material.

Diamond is normally an electrical insulator, but becomes a semiconductor when doped with the right impurities. Diamond film is tougher than silicon, so it could be useful for devices that must operate at high temperatures or under other harsh conditions.
However, diamond films are expensive and difficult to make. They are produced by vaporising organic material, and then controlling how the carbon atoms crystallise onto a surface. The process works best if the material contains carbon and oxygen in roughly equal parts, as well as some hydrogen.

Now a team of researchers led by Javier Morales of the University of Nueva Leon near Monterrey in Mexico have shown that ordinary tequila does the job nicely. They injected the heated vapour from 80-proof "tequila blanco" into a low-pressure chamber. Measurements confirmed that the carbon deposited on test surfaces had a diamond structure (www.arxiv.org/abs/0806.1485). "Some kinds of tequila seem naturally to have the right mix of atoms," says Morales. Other forms of alcohol have also worked, although it's not clear if this is faster or more reliable than using common precursors such as acetone.

"The result is certainly funny, but the process seems reasonable," says physicist Rudolf Pfeiffer of the University of Vienna in Austria. "I don't know of any previous attempts to make diamonds from drinks."
_________________________
Helice

Nemo me impune lacesset.
~~~~~~~~~~~~~~~~

"Of all the tyrannies that affect mankind, tyranny in
religion is the worst; every other species of tyranny is
limited to the world we live in; but this attempts to
stride beyond the grave, and seeks to pursue us into
eternity."

-- Thomas Paine

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#272764 - 06/20/08 11:42 PM Re: Tequila!! [Re: Helice]
Bad Bird Offline
experienced member

Registered: 02/17/08
Loc: WA, USA
Thanks for the URL. I've bookmarked the site.

Up until last Nov. I used to read the paper version of NewScientist avidly, but it was free (my former employer has for years purchased various technology magazines that were circulated among interested employees). Even science can have slightly different slants and the British view came through.

Their site also had a bit and video on "Tin Pest". One of our researchers had been working on "Tin Whisker" growth which is a different manifestation of what the Brits are calling Tin Pest. The problem is that the EU has mandated that lead not be used in making circuit board assemblies--no Lead-based solder allowed. This is big problem for US companies that sell products containing electronics globally (such as airplanes) as the alternatives are tin-based. Over time, particularly in high humidity, the tin grows whiskers that eventually reach another trace and short out the circuit board. Even conformal coating (spraying a plastic coating over the completed board) doesn't completely prevent it. There is another problem, too. It seems that the no-lead solders are much more susceptible to fatigue cracking when subjected long-term low level vibration: a definite reliability problem, especially for engine-driven vehicles.

Getting somewhat back to the subject, which seems to be weird solutions to technical problems: The Polaris missile uses a device to start its solid rocket motors that looks rather like a phallus. The pyrotechnic in it tends to absorb water, which can cause it to fizzle. When it ignites it spews flame out the end to light the main solid propellant. What do you think is used to provide a weather seal? :gasp:

I'll drink to that!
_________________________
Bad Bird


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#272775 - 06/21/08 03:12 AM Re: Tequila!! [Re: Helice]
Elena Moderator Offline
Sci/Tech Moderator

Registered: 07/10/05
Loc: Moscow, Russia
Great!!! But how did they hit upon it?
_________________________
"It is better to be roughly right than precisely wrong"

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#272779 - 06/21/08 03:56 AM Re: Tequila!! [Re: Elena]
Helice Administrator Offline
Administrator

Registered: 09/01/97
Loc: CT, US
Elena,

The article says they need to vaporize organic material that contains C H O , with Carbon and Oxygen present in roughly equal proportions, and a little hydrogen. They vaporize it at high heat and let the vapor crystalize on a special surface under low pressure to produce the diamond film.

Many types of alcohol have precisely what is required, so I supposed a little bit of experimenting went on. smile

It's controlling and 'persuading' the carbon atoms to crystalize exactly the right way that's crucial... it makes the difference whether you end up with a film of diamond or graphite, which are chemically identical, but have a different crystalline structure.
_________________________
Helice

Nemo me impune lacesset.
~~~~~~~~~~~~~~~~

"Of all the tyrannies that affect mankind, tyranny in
religion is the worst; every other species of tyranny is
limited to the world we live in; but this attempts to
stride beyond the grave, and seeks to pursue us into
eternity."

-- Thomas Paine

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#272780 - 06/21/08 05:14 AM Re: Tequila!! [Re: Helice]
Elena Moderator Offline
Sci/Tech Moderator

Registered: 07/10/05
Loc: Moscow, Russia
Quote:
Many types of alcohol have precisely what is required, so I supposed a little bit of experimenting went on. smile

I wonder would vodka suit better? laugh


Edited by Elena (06/21/08 05:16 AM)
_________________________
"It is better to be roughly right than precisely wrong"

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#272781 - 06/21/08 05:27 AM Re: Tequila!! [Re: Elena]
Helice Administrator Offline
Administrator

Registered: 09/01/97
Loc: CT, US
It might be so; but would you rather burn up good vodka or a bottle ot requila, Elana? wink
_________________________
Helice

Nemo me impune lacesset.
~~~~~~~~~~~~~~~~

"Of all the tyrannies that affect mankind, tyranny in
religion is the worst; every other species of tyranny is
limited to the world we live in; but this attempts to
stride beyond the grave, and seeks to pursue us into
eternity."

-- Thomas Paine

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#272842 - 06/21/08 02:29 PM Re: Tequila!! [Re: Helice]
Chocolategenii Offline
Domestic Affairs Moderator

Registered: 10/03/06
Loc: California
Save your old bottles .......... They are lined with diamonds :smirk:
_________________________
"All things are our relatives; what we do to everything, we do to ourselves. All is really ONE."
Lakota leader Black Elk

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